
The plates carry opposite charges, so the field between them runs from the positive plate at the top to the negative plate at the bottom: \(\displaystyle \vec{E}\) points
downward.
The force on a charge in that field is \(\displaystyle \vec{F} = q\vec{E}\), so
a positive charge is pushed along \(\displaystyle \vec{E}\) — down, toward the negative plate;
a negative charge is pushed against \(\displaystyle \vec{E}\) — up, toward the positive plate.
Reading the tracks against that:
Tracks $\displaystyle 1$ and $\displaystyle 2$ bend upward, toward the positive plate, so charges $\displaystyle 1$ and $\displaystyle 2$ are negative.
Track $\displaystyle 3$ bends downward, toward the negative plate, so charge $\displaystyle 3$ is positive.
Charge-to-mass ratio. Inside the plates each particle keeps its horizontal speed \(\displaystyle v\) and picks up a vertical acceleration
\[a = \frac{qE}{m}\]
Crossing a field region of length \(\displaystyle L\) takes a time \(\displaystyle t = L/v\), so the sideways deflection on leaving the plates is
\[y = \tfrac{1}{2}\,a\,t^{2} = \frac{1}{2}\left(\frac{q}{m}\right)\frac{EL^{2}}{v^{2}}\]
All three particles cross the same field over the same length, so for comparable entry speeds
\[y \;\propto\; \frac{q}{m}\]
and the particle deflected most inside the plates has the largest charge-to-mass ratio.
Track
$\displaystyle 3$ is deflected most while between the plates, so
particle $\displaystyle 3$ has the highest charge-to-mass ratio.
Note the deflection must be judged
inside the plates, not from where the tracks end at the right of the figure. Beyond the plates there is no field and each particle travels in a straight line, so a small exit angle keeps adding displacement with distance — track $\displaystyle 1$ finishes furthest from where it started, but it bent less while the field was acting on it.