Exercise 17
Why are elemental dopants for Silicon or Germanium usually chosen from group XIII or group XV?
NCERT’s answer
The size of dopant atoms should be such as not to distort the pure semiconductor lattice structure and yet easily contribute a charge carrier on forming co-valent bonds with Si or Ge.
Similar size, so they replace Si/Ge atoms without distorting the lattice.\[\text{Group XV: } 5\,e^- \to 4\ \text{bonds} + 1\ \text{free } e^- \Rightarrow \text{n-type (donor)} \]\[\text{Group XIII: } 3\,e^- \to 3\ \text{bonds} + 1\ \text{hole} \Rightarrow \text{p-type (acceptor)} \]Answer: Similar atomic size, and one valence electron more (XV) or fewer (XIII) than four, giving a free electron or a hole.