Exercise 5.5
The label on a cooking oil pack says one litre ( g). If this oil is mixed with water, will it form a separate layer? If so, which substance will be on top? How will you separate the two layers? Also, draw the diagram of the apparatus used.
Not cross-checked
NCERT prints no numerical answer for this exercise, so this working has not been cross-checked against the book.
Yes, two separate layers form, with the oil on top, and the two are separated using a separating funnel.
Oil and water are immiscible, so they never form a single uniform liquid however much they are shaken.
One litre of the oil has a mass of $\displaystyle 910$ g while one litre of water has a mass of about $\displaystyle 1000$ g, so the oil is the lighter liquid: \(\displaystyle \text{density of oil} = \dfrac{910\ \text{g}}{1000\ \text{mL}} = 0.91\ \text{g/mL} \) against \(\displaystyle 1\ \text{g/mL} \) for water.
The less dense liquid floats, so oil is the upper layer and water the lower layer.
Method: pour the mixture into a separating funnel, close the stopper and let it stand undisturbed until the boundary between the layers is sharp; open the stopcock slowly and run the lower water layer into a beaker; close the stopcock when the water is almost drained; discard the small middle portion that contains both liquids; then open the stopcock again and collect the oil in a separate vessel.
Diagram to draw: a pear-shaped separating funnel clamped upright in a laboratory stand, a glass stopper at the top, the funnel showing two layers separated by a straight horizontal boundary — the upper one labelled oil and the lower one labelled water — the narrow stem below carrying the stopcock, and a conical flask placed under the stem to receive the liquid that is run off. Every one of those seven parts must be labelled with a leader line.