One card is drawn from $\displaystyle 52$, so every probability below is (number of favourable cards)/52. In each part test whether \(\displaystyle \mathrm{P}(\mathrm{E}\cap\mathrm{F})=\mathrm{P}(\mathrm{E})\,\mathrm{P}(\mathrm{F})\).
(i) E: spade, F: ace. There are $\displaystyle 13$ spades and $\displaystyle 4$ aces, and \(\displaystyle \mathrm{E}\cap\mathrm{F}\) is the single card 'ace of spades':
\[\mathrm{P}(\mathrm{E})=\frac{13}{52}=\frac{1}{4},\quad \mathrm{P}(\mathrm{F})=\frac{4}{52}=\frac{1}{13},\quad \mathrm{P}(\mathrm{E}\cap\mathrm{F})=\frac{1}{52}. \]
\[\mathrm{P}(\mathrm{E})\,\mathrm{P}(\mathrm{F})=\frac{1}{4}\times\frac{1}{13}=\frac{1}{52}=\mathrm{P}(\mathrm{E}\cap\mathrm{F})\ \Rightarrow\ \textbf{independent}. \]
(ii) E: black, F: king. There are $\displaystyle 26$ black cards and $\displaystyle 4$ kings; \(\displaystyle \mathrm{E}\cap\mathrm{F}\) is the two black kings:
\[\mathrm{P}(\mathrm{E})=\frac{26}{52}=\frac{1}{2},\quad \mathrm{P}(\mathrm{F})=\frac{4}{52}=\frac{1}{13},\quad \mathrm{P}(\mathrm{E}\cap\mathrm{F})=\frac{2}{52}=\frac{1}{26}. \]
\[\mathrm{P}(\mathrm{E})\,\mathrm{P}(\mathrm{F})=\frac{1}{2}\times\frac{1}{13}=\frac{1}{26}=\mathrm{P}(\mathrm{E}\cap\mathrm{F})\ \Rightarrow\ \textbf{independent}. \]
(iii) E: king or queen, F: queen or jack. Each of E and F contains \(\displaystyle 4+4=8\) cards, and their overlap is exactly the $\displaystyle 4$ queens:
\[\mathrm{P}(\mathrm{E})=\frac{8}{52}=\frac{2}{13},\quad \mathrm{P}(\mathrm{F})=\frac{8}{52}=\frac{2}{13},\quad \mathrm{P}(\mathrm{E}\cap\mathrm{F})=\frac{4}{52}=\frac{1}{13}. \]
\[\mathrm{P}(\mathrm{E})\,\mathrm{P}(\mathrm{F})=\frac{2}{13}\times\frac{2}{13}=\frac{4}{169}\neq\frac{13}{169}=\frac{1}{13}=\mathrm{P}(\mathrm{E}\cap\mathrm{F})\ \Rightarrow\ \textbf{not independent}. \]
So E and F are independent in cases (i) and (ii), and not independent in case (iii).