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Chemistry · 2017
JEE Main 2017 · 2017-04-02 Offline · Q31
Given C_(graphite) + O_2( g ) → CO_2( g ); Δ_r H^°=-393.5 kJ mol^-1; H_2( g )+1/2 O_2( g ) → H_2 O ( l ); Δ_r H^°=-285.8 kJ mol^-1; CO_2( g )+2 H_2 O…
Given
$$\begin{aligned}
& \mathrm{C}_{\text {(graphite) }}+\mathrm{O}_2(\mathrm{~g}) \rightarrow \mathrm{CO}_2(\mathrm{~g}) ; \\
& \Delta_{\mathrm{r}} \mathrm{H}^{\circ}=-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}
\end{aligned}
$$
$$\begin{aligned}
& \mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow \mathrm{H}_2 \mathrm{O}(\mathrm{l}) ; \\
& \Delta_{\mathrm{r}} \mathrm{H}^{\circ}=-285.8 \mathrm{~kJ} \mathrm{~mol}^{-1}
\end{aligned}
$$
$$\begin{aligned}
& \mathrm{CO}_2(\mathrm{~g})+2 \mathrm{H}_2 \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{CH}_4(\mathrm{~g})+2 \mathrm{O}_2(\mathrm{~g}) ; \\
& \Delta_{\mathrm{r}} \mathrm{H}^{\circ}=+890.3 \mathrm{~kJ} \mathrm{~mol}^{-1}
\end{aligned}
$$
Based on the above thermochemical equations, the value of $\displaystyle \Delta_{\mathrm{r}} \mathrm{H}^{\circ}$ at $\displaystyle 298$ K for the reaction
$$\mathrm{C}_{\text {(graphite) }}+2 \mathrm{H}_2(\mathrm{~g}) \rightarrow \mathrm{CH}_4(\mathrm{~g}) \text { will be : }
$$
Official answer
(1)
$\displaystyle -74.8 \mathrm{~kJ} \mathrm{~mol}^{-1}$
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JEE Main 2017 Chemistry question, with the answer from NTA’s final answer key. Where our answers come from.