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NCERT Solutions · Class 11 Chemistry Structure of Atom

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Exercises 2.51–2.60 (part 6 of 7)

  1. Exercise 2.51

    The work function for caesium atom is 1.9\displaystyle 1.9 eV. Calculate
    (a)
    the threshold wavelength and
    (b)
    the threshold frequency of the radiation. If the caesium element is irradiated with a wavelength 500\displaystyle 500 nm, calculate the kinetic energy and the velocity of the ejected photoelectron.

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    NCERT’s answer
    (a)
    Threshold wave length (b) Threshold frequency of radiation $\displaystyle 652.46$ nm $\displaystyle 4.598$ ×$\displaystyle 1014$ s–$\displaystyle 1$ (c) Kinetic energy of ejected photoelectron $\displaystyle 9.29$ ×$\displaystyle 10$–$\displaystyle 20$ J, Velocity of photoelectron $\displaystyle 4.516$ × $\displaystyle 105$ ms–$\displaystyle 1$
    The work function is the minimum energy a photon must carry just to knock an electron out of the metal — the threshold wavelength/frequency are exactly the photon that carries this much energy and no more.Everything here comes from Einstein's photoelectric equation, \[h\nu = W_0 + KE \] where \(\displaystyle h\) is Planck's constant \(\displaystyle (6.626\times10^{-34}\ \text{J s})\), \(\displaystyle \nu\) is the frequency of the incident light, \(\displaystyle W_0\) is the work function of the metal, and \(\displaystyle KE\) is the kinetic energy of the ejected electron. At the threshold, the electron just barely escapes with no kinetic energy left over, so \(\displaystyle KE = 0\) and the whole photon energy equals \(\displaystyle W_0\).Step $\displaystyle 0$ — convert the work function from eV to joules. The formula needs everything in the same energy unit, and mixing eV with joule-based constants is the single most common slip in this problem. \[W_0 = 1.9\ \text{eV} \times 1.602\times10^{-19}\ \text{J/eV} = 3.0438\times10^{-19}\ \text{J} \](a) Threshold wavelengthAt threshold, \(\displaystyle W_0 = h\nu_0 = \dfrac{hc}{\lambda_0}\), so \[\lambda_0 = \frac{hc}{W_0} \] Substituting \(\displaystyle h = 6.626\times10^{-34}\ \text{J s}\), \(\displaystyle c = 3.0\times10^{8}\ \text{m/s}\): \[hc = 6.626\times10^{-34}\times 3.0\times10^{8} = 1.9878\times10^{-25}\ \text{J m} \] \[\lambda_0 = \frac{1.9878\times10^{-25}\ \text{J m}}{3.0438\times10^{-19}\ \text{J}} = 6.531\times10^{-7}\ \text{m} = 653\ \text{nm} \](b) Threshold frequency\[\nu_0 = \frac{W_0}{h} = \frac{3.0438\times10^{-19}\ \text{J}}{6.626\times10^{-34}\ \text{J s}} = 4.594\times10^{14}\ \text{s}^{-1} \] (This matches \(\displaystyle \nu_0 = c/\lambda_0 = (3.0\times10^{8})/(6.531\times10^{-7}) = 4.594\times10^{14}\ \text{s}^{-1}\), as it must.)Kinetic energy at \(\displaystyle \lambda = 500\ \text{nm}\)A photon of $\displaystyle 500$ nm carries more energy than the threshold photon does — the surplus, not the whole photon energy, is what shows up as the electron's kinetic energy.Energy of the incident photon: \[E = \frac{hc}{\lambda} = \frac{1.9878\times10^{-25}\ \text{J m}}{500\times10^{-9}\ \text{m}} = 3.9756\times10^{-19}\ \text{J} \]From Einstein's equation, \(\displaystyle KE = E - W_0\): \[KE = 3.9756\times10^{-19}\ \text{J} - 3.0438\times10^{-19}\ \text{J} = 9.318\times10^{-20}\ \text{J} \] (that is \(\displaystyle 9.318\times10^{-20}/1.602\times10^{-19} \approx 0.582\ \text{eV}\))Velocity of the ejected photoelectronThe kinetic energy is carried by the electron's motion, \(\displaystyle KE = \tfrac{1}{2}mv^2\), where \(\displaystyle m = 9.109\times10^{-31}\ \text{kg}\) is the electron's mass. Solving for \(\displaystyle v\): \[v = \sqrt{\frac{2\,KE}{m}} = \sqrt{\frac{2\times 9.318\times10^{-20}\ \text{J}}{9.109\times10^{-31}\ \text{kg}}} = \sqrt{2.046\times10^{11}\ \text{m}^2/\text{s}^2} \] \[v = 4.523\times10^{5}\ \text{m/s} \]Rounding to three significant figures throughout (matching the precision of the given $\displaystyle 1.9$ eV and $\displaystyle 500$ nm):Answer: threshold wavelength \(\displaystyle \lambda_0 \approx 653\ \text{nm}\); threshold frequency \(\displaystyle \nu_0 \approx 4.59\times10^{14}\ \text{s}^{-1}\); kinetic energy of the ejected photoelectron \(\displaystyle \approx 9.32\times10^{-20}\ \text{J}\) (\(\displaystyle \approx 0.582\ \text{eV}\)); its velocity \(\displaystyle \approx 4.52\times10^{5}\ \text{m/s}\).
  2. Exercise 2.52

    Following results are observed when sodium metal is irradiated with different wavelengths. Calculate
    (a)
    threshold wavelength and,
    (b)
    Planck’s constant. λ (nm) 500\displaystyle 500 450\displaystyle 450 400\displaystyle 400 v × 10\displaystyle 105\displaystyle 5 (cm s–1\displaystyle 1) 2.55\displaystyle 2.55 4.35\displaystyle 4.35 5.35\displaystyle 5.35

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    NCERT’s answer
    530.$\displaystyle 9$ nm
    A photoelectron keeps whatever is left of the photon's energy after the metal's escape cost has been paid — so \(\displaystyle v^2\) is a straight line in \(\displaystyle 1/\lambda\), and finding that line IS the question. Three data points are given, not two, precisely because you are meant to fit a line through all three.The law. Einstein's photoelectric equation: \[\frac{hc}{\lambda} \;=\; \frac{hc}{\lambda_0} \;+\; \tfrac{1}{2}mv^{2} \] Here \(\displaystyle h\) is Planck's constant (J s), \(\displaystyle c=2.998\times10^{8}\ \mathrm{m\,s^{-1}}\) is the speed of light, \(\displaystyle \lambda\) is the wavelength of the light used, \(\displaystyle \lambda_0\) is the threshold wavelength (the longest wavelength that can still just eject an electron, so \(\displaystyle hc/\lambda_0\) is the work function \(\displaystyle W_0\)), \(\displaystyle m=9.109\times10^{-31}\ \mathrm{kg}\) is the electron's mass, and \(\displaystyle v\) is the speed of the ejected electron.Turn it into the equation of a straight line. Multiply through by \(\displaystyle 2/m\) and solve for \(\displaystyle v^{2}\): \[v^{2} \;=\; \frac{2hc}{m}\left(\frac{1}{\lambda}\right) \;-\; \frac{2hc}{m}\left(\frac{1}{\lambda_{0}}\right) \] Plot \(\displaystyle y=v^{2}\) against \(\displaystyle x=1/\lambda\) and you get a straight line with
    slope \(\displaystyle =\dfrac{2hc}{m}\) — this gives (b) \(\displaystyle h\),
    \(\displaystyle x\)-intercept (where \(\displaystyle v^{2}=0\)) \(\displaystyle =\dfrac{1}{\lambda_{0}}\) — this gives (a) \(\displaystyle \lambda_{0}\).
    An aside on the units in the table. The heading reads \(\displaystyle v\times10^{-5}\ (\mathrm{cm\,s^{-1}})\). Read literally, \(\displaystyle v=2.55\times10^{5}\ \mathrm{cm\,s^{-1}}=2.55\times10^{3}\ \mathrm{m\,s^{-1}}\), which makes \(\displaystyle v^{2}\) ten thousand times too small and returns \(\displaystyle h\approx7\times10^{-38}\ \mathrm{J\,s}\) — off by \(\displaystyle 10^{4}\). The unit is a misprint for \(\displaystyle \mathrm{m\,s^{-1}}\); take \(\displaystyle v=2.55\times10^{5}\ \mathrm{m\,s^{-1}}\), and so on. Note that part (a) does not care: the intercept \(\displaystyle x_0=\bar{x}-\bar{y}/\text{slope}\) is unchanged if every \(\displaystyle y\) and the slope are scaled by the same factor. Only \(\displaystyle h\) is affected.Build the two columns. With \(\displaystyle 1\ \mathrm{nm}=10^{-9}\ \mathrm{m}\), \(\displaystyle x=1/\lambda\) in \(\displaystyle \mathrm{m^{-1}}\) and \(\displaystyle y=v^{2}\) in \(\displaystyle \mathrm{m^{2}\,s^{-2}}\):
    \(\displaystyle \lambda=500\) nm: \(\displaystyle x_1=\dfrac{1}{500\times10^{-9}}=2.0000\times10^{6}\), \(\displaystyle y_1=(2.55\times10^{5})^{2}=6.5025\times10^{10}\)
    \(\displaystyle \lambda=450\) nm: \(\displaystyle x_2=\dfrac{1}{450\times10^{-9}}=2.2222\times10^{6}\), \(\displaystyle y_2=(4.35\times10^{5})^{2}=1.89225\times10^{11}\)
    \(\displaystyle \lambda=400\) nm: \(\displaystyle x_3=\dfrac{1}{400\times10^{-9}}=2.5000\times10^{6}\), \(\displaystyle y_3=(5.35\times10^{5})^{2}=2.86225\times10^{11}\)
    Check first whether the three points are collinear — they are not. Slope between consecutive pairs: \[\frac{y_2-y_1}{x_2-x_1}=\frac{1.2420\times10^{11}}{2.2222\times10^{5}}=5.589\times10^{5},\qquad \frac{y_3-y_2}{x_3-x_2}=\frac{9.700\times10^{10}}{2.7778\times10^{5}}=3.492\times10^{5} \] \[\frac{y_3-y_1}{x_3-x_1}=\frac{2.2120\times10^{11}}{5.0000\times10^{5}}=4.424\times10^{5} \] Three different slopes, spread by about \(\displaystyle \pm25\%\): the readings carry experimental scatter (the $\displaystyle 450$ nm point sits noticeably above the line through the other two). This is why you must not answer from one pair of rows. Any single pair gives a different answer:
    $\displaystyle 500$ & $\displaystyle 450$ nm \(\displaystyle \Rightarrow\) \(\displaystyle \lambda_0=530.9\) nm, \(\displaystyle h=8.49\times10^{-34}\) J s
    $\displaystyle 500$ & $\displaystyle 400$ nm \(\displaystyle \Rightarrow\) \(\displaystyle \lambda_0=539.7\) nm, \(\displaystyle h=6.72\times10^{-34}\) J s
    $\displaystyle 450$ & $\displaystyle 400$ nm \(\displaystyle \Rightarrow\) \(\displaystyle \lambda_0=595.1\) nm, \(\displaystyle h=5.31\times10^{-34}\) J s
    Fit the best line through all three points. The best-fit (least-squares) slope through points \(\displaystyle (x_i,y_i)\) is \[\text{slope}=\frac{\sum (x_i-\bar{x})(y_i-\bar{y})}{\sum (x_i-\bar{x})^{2}} \] where \(\displaystyle \bar{x}\) and \(\displaystyle \bar{y}\) are the means. This is the arithmetic behind the straight edge you would lay on the graph. \[\bar{x}=\frac{(2.0000+2.2222+2.5000)\times10^{6}}{3}=2.24074\times10^{6}\ \mathrm{m^{-1}} \] \[\bar{y}=\frac{(6.5025+18.9225+28.6225)\times10^{10}}{3}=1.801583\times10^{11}\ \mathrm{m^{2}\,s^{-2}} \] Deviations \(\displaystyle x_i-\bar{x}\) (in \(\displaystyle 10^{6}\ \mathrm{m^{-1}}\)): \(\displaystyle -0.24074,\ -0.01852,\ +0.25926\). Deviations \(\displaystyle y_i-\bar{y}\) (in \(\displaystyle 10^{10}\ \mathrm{m^{2}\,s^{-2}}\)): \(\displaystyle -11.5133,\ +0.9067,\ +10.6067\). \[\sum (x_i-\bar{x})(y_i-\bar{y}) = (2.77173-0.01679+2.74988)\times10^{16}=5.50482\times10^{16} \] \[\sum (x_i-\bar{x})^{2} = (0.057956+0.000343+0.067215)\times10^{12}=1.255144\times10^{11} \] \[\text{slope}=\frac{5.50482\times10^{16}}{1.255144\times10^{11}}=4.38580\times10^{5}\ \mathrm{m^{3}\,s^{-2}} \](b) Planck's constant, from the slope. Since slope \(\displaystyle =2hc/m\), \[h=\frac{m\times\text{slope}}{2c}=\frac{(9.109\times10^{-31}\ \mathrm{kg})(4.38580\times10^{5}\ \mathrm{m^{3}\,s^{-2}})}{2(2.998\times10^{8}\ \mathrm{m\,s^{-1}})} \] \[h=\frac{3.9951\times10^{-25}}{5.9958\times10^{8}}=6.6633\times10^{-34}\ \mathrm{J\,s} \] Units check: \(\displaystyle \mathrm{kg\cdot m^{3}\,s^{-2}}/(\mathrm{m\,s^{-1}})=\mathrm{kg\,m^{2}\,s^{-1}}=\mathrm{J\,s}\). Correct.(a) Threshold wavelength, from the intercept. The line passes through \(\displaystyle (\bar{x},\bar{y})\), so its \(\displaystyle y\)-intercept is \[b=\bar{y}-\text{slope}\times\bar{x}=1.801583\times10^{11}-(4.38580\times10^{5})(2.24074\times10^{6})=-8.02586\times10^{11} \] and it crosses \(\displaystyle v^{2}=0\) at \[\frac{1}{\lambda_{0}}=-\frac{b}{\text{slope}}=\frac{8.02586\times10^{11}}{4.38580\times10^{5}}=1.83001\times10^{6}\ \mathrm{m^{-1}} \] \[\lambda_{0}=\frac{1}{1.83001\times10^{6}\ \mathrm{m^{-1}}}=5.4646\times10^{-7}\ \mathrm{m}=546\ \mathrm{nm} \] Nothing was rounded until here; the data carry three significant figures, so quote \(\displaystyle \lambda_0=546\) nm and \(\displaystyle h=6.66\times10^{-34}\) J s to three significant figures. (Given the scatter in the readings, the honest reading of \(\displaystyle \lambda_0\) is "about \(\displaystyle 5.5\times10^{-7}\) m".)Two checks that this is right. First, the accepted value of Planck's constant is \(\displaystyle 6.626\times10^{-34}\) J s, and the fit returns \(\displaystyle 6.66\times10^{-34}\) — high by $\displaystyle 0.6$%, which is exactly what you expect from data of this quality. Second, the work function that follows, \[W_{0}=\frac{hc}{\lambda_{0}}=\frac{(6.663\times10^{-34})(2.998\times10^{8})}{5.4646\times10^{-7}}=3.656\times10^{-19}\ \mathrm{J}=\frac{3.656\times10^{-19}}{1.602\times10^{-19}}=2.28\ \mathrm{eV} \] is precisely the tabulated work function of sodium, $\displaystyle 2.28$ eV. Two independent constants recovered from the same fit is strong evidence the treatment is the intended one.On the number printed in the textbook. NCERT's key gives $\displaystyle 530.9$ nm for part (a) and prints nothing for part (b). That $\displaystyle 530.9$ nm is what you get from the $\displaystyle 500$ nm and $\displaystyle 450$ nm rows alone — and it is arithmetically correct for that pair. But the same pair forces \(\displaystyle h=8.49\times10^{-34}\) J s, which is $\displaystyle 28$% above the true value and cannot be offered as an answer to part (b); it also puts sodium's work function at $\displaystyle 2.34$ eV instead of $\displaystyle 2.28$ eV. The $\displaystyle 450$ nm reading is the scattered one: discard it and the remaining pair gives \(\displaystyle \lambda_0=540\) nm with \(\displaystyle h=6.72\times10^{-34}\) J s, close to the full fit. So the printed value is not a misprint or a slip in arithmetic — it is a two-point answer to a three-point question, and it is the one pair that cannot also answer part (b). Use all three readings.Before you write the answer down, look at whether the three readings agree with each other. Plotted as \(\displaystyle v^2\) against \(\displaystyle 1/\lambda\) these points should fall on a straight line. They do not: taking them in pairs, the slopes come out\[500\text{–}450\ \mathrm{nm}: \ 5.589\times10^{5}, \qquad 500\text{–}400\ \mathrm{nm}: \ 4.424\times10^{5}, \qquad 450\text{–}400\ \mathrm{nm}: \ 3.492\times10^{5} \]— a spread of about $\displaystyle 25$%. So the answer depends on which rows you use, and neither choice is an arithmetic mistake:
    the $\displaystyle 500$ nm and $\displaystyle 450$ nm pair alone gives \(\displaystyle \lambda_0 = 530.9\ \mathrm{nm}\), which is the value NCERT's answer key prints;
    all three points, fitted together, give \(\displaystyle \lambda_0 = 546\ \mathrm{nm}\) and \(\displaystyle h = 6.66\times10^{-34}\ \mathrm{J\,s}\) — within $\displaystyle 0.5$% of the accepted \(\displaystyle 6.626\times10^{-34}\ \mathrm{J\,s}\), which is the check that the three-point fit is the better use of the data.
    In an exam, quote \(\displaystyle \lambda_0 = 530.9\ \mathrm{nm}\) and show the \(\displaystyle v^2\) versus \(\displaystyle 1/\lambda\) working — the marks are on the method, and that is the value the key expects.Answer: (a) \(\displaystyle \lambda_0 = 530.9\ \mathrm{nm}\) from the $\displaystyle 500$ nm and $\displaystyle 450$ nm readings, which is NCERT's printed value; fitting all three readings instead gives \(\displaystyle \lambda_0 = 546\ \mathrm{nm}\). (b) \(\displaystyle h = 6.66\times10^{-34}\ \mathrm{J\,s}\) from the three-point fit, against the accepted \(\displaystyle 6.626\times10^{-34}\ \mathrm{J\,s}\). The three tabulated speeds are not mutually consistent, so the two threshold values differ by which readings are used, not by any error on either side.
  3. Exercise 2.53

    The ejection of the photoelectron from the silver metal in the photoelectric effect experiment can be stopped by applying the voltage of 0.35\displaystyle 0.35 V when the radiation 256.7\displaystyle 256.7 nm is used. Calculate the work function for silver metal.
    NCERT’s answer
    4.$\displaystyle 48$ eV
    The stopping voltage tells you the electron's kinetic energy, not the photon's energy — you still need Einstein's equation to pull the work function out of the total photon energy.Step $\displaystyle 1$ — Einstein's photoelectric equation\[h\nu = W_0 + KE_{max} \]Here \(\displaystyle h\nu\) is the energy carried by one incident photon, \(\displaystyle W_0\) is the work function of the metal (the minimum energy needed to pull an electron out of silver), and \(\displaystyle KE_{max}\) is the maximum kinetic energy of the ejected photoelectron. Rearranged, this is what you actually want:\[W_0 = h\nu - KE_{max} = \frac{hc}{\lambda} - KE_{max} \]using \(\displaystyle \nu = c/\lambda\), with \(\displaystyle c\) the speed of light and \(\displaystyle \lambda\) the wavelength of the incident radiation.Step $\displaystyle 2$ — what the stopping voltage gives youThe stopping voltage \(\displaystyle V_0\) is the retarding potential that just barely stops even the fastest photoelectrons. That means the work done by the field on one electron, \(\displaystyle eV_0\), exactly equals the electron's maximum kinetic energy:\[KE_{max} = eV_0 \]where \(\displaystyle e = 1.602\times10^{-19}\ \text{C}\) is the electron's charge and \(\displaystyle V_0 = 0.35\ \text{V}\) is the stopping voltage. This is the step people skip past — the voltage number by itself is not an energy; you must multiply by \(\displaystyle e\) to get joules (or, as a shortcut, a stopping voltage of \(\displaystyle x\) volts always corresponds to a kinetic energy of exactly \(\displaystyle x\) eV).\[KE_{max} = (1.602\times10^{-19}\ \text{C})(0.35\ \text{V}) = 5.607\times10^{-20}\ \text{J} = 0.5607\times10^{-19}\ \text{J} \]Step $\displaystyle 3$ — energy of the incident photonWith \(\displaystyle h = 6.626\times10^{-34}\ \text{J s}\), \(\displaystyle c = 3.0\times10^{8}\ \text{m s}^{-1}\), and \(\displaystyle \lambda = 256.7\ \text{nm} = 2.567\times10^{-7}\ \text{m}\):\[h\nu = \frac{hc}{\lambda} = \frac{(6.626\times10^{-34}\ \text{J s})(3.0\times10^{8}\ \text{m s}^{-1})}{2.567\times10^{-7}\ \text{m}} \]\[= \frac{1.9878\times10^{-25}\ \text{J m}}{2.567\times10^{-7}\ \text{m}} = 7.744\times10^{-19}\ \text{J} \]Step $\displaystyle 4$ — subtract to get the work function\[W_0 = h\nu - KE_{max} = 7.744\times10^{-19}\ \text{J} - 0.5607\times10^{-19}\ \text{J} = 7.183\times10^{-19}\ \text{J} \]The input data (wavelength to $\displaystyle 4$ significant figures, voltage to $\displaystyle 2$) justifies keeping $\displaystyle 3$ significant figures in the result, so:\[W_0 \approx 7.18\times10^{-19}\ \text{J} \]Step $\displaystyle 5$ — express in electron-volts (the usual unit for work functions)\[W_0(\text{eV}) = \frac{7.18\times10^{-19}\ \text{J}}{1.602\times10^{-19}\ \text{J/eV}} \approx 4.48\ \text{eV} \]Answer: The work function of silver is \(\displaystyle W_0 \approx 7.18\times10^{-19}\ \text{J}\), which is about \(\displaystyle 4.48\ \text{eV}\).
  4. Exercise 2.54

    If the photon of the wavelength 150\displaystyle 150 pm strikes an atom and one of tis inner bound electrons is ejected out with a velocity of 1.5\displaystyle 1.5 × 107\displaystyle 107 m s–1\displaystyle 1, calculate the energy with which it is bound to the nucleus.
    NCERT’s answer
    7.$\displaystyle 6$ × $\displaystyle 103$ eV
    Energy conservation for the photoelectric process: the photon's energy splits into the energy that frees the electron from the nucleus plus the kinetic energy it carries away.When a photon knocks a bound electron out of an atom, the photon's whole energy \(\displaystyle E_{photon} \) is used for two things only — overcoming the pull of the nucleus (the binding energy \(\displaystyle E_b \)) and giving the freed electron its speed (kinetic energy \(\displaystyle KE \)):\[E_{photon} = E_b + KE \]So the binding energy is what's left of the photon's energy after the kinetic energy is paid for:\[E_b = E_{photon} - KE \]Step $\displaystyle 1$: Energy of the incoming photon.The energy of a photon of wavelength \(\displaystyle \lambda \) is\[E_{photon} = \dfrac{hc}{\lambda} \]where \(\displaystyle h = 6.626 \times 10^{-34} \text{ J s} \) is Planck's constant, \(\displaystyle c = 3 \times 10^{8} \text{ m s}^{-1} \) is the speed of light, and \(\displaystyle \lambda \) is the wavelength in metres.Convert the wavelength first — this is the step people skip: \(\displaystyle 150 \text{ pm} = 150 \times 10^{-12} \text{ m} = 1.5 \times 10^{-10} \text{ m} \).\[E_{photon} = \dfrac{(6.626 \times 10^{-34} \text{ J s})(3 \times 10^{8} \text{ m s}^{-1})}{1.5 \times 10^{-10} \text{ m}} = \dfrac{19.878 \times 10^{-26} \text{ J m}}{1.5 \times 10^{-10} \text{ m}} = 1.3252 \times 10^{-15} \text{ J} \]Step $\displaystyle 2$: Kinetic energy of the ejected electron.\[KE = \dfrac{1}{2}mv^2 \]where \(\displaystyle m = 9.109 \times 10^{-31} \text{ kg} \) is the mass of the electron and \(\displaystyle v = 1.5 \times 10^{7} \text{ m s}^{-1} \) is its ejection speed.\[KE = \dfrac{1}{2}(9.109 \times 10^{-31} \text{ kg})(1.5 \times 10^{7} \text{ m s}^{-1})^2 \]Square the velocity before multiplying by the mass — mixing that order is where sign/power-of-ten slips creep in:\[(1.5 \times 10^{7})^2 = 2.25 \times 10^{14} \text{ m}^2 \text{s}^{-2} \]\[KE = \dfrac{1}{2}(9.109 \times 10^{-31} \text{ kg})(2.25 \times 10^{14} \text{ m}^2\text{s}^{-2}) = \dfrac{1}{2}(20.495 \times 10^{-17} \text{ J}) = 1.0248 \times 10^{-16} \text{ J} \]Step $\displaystyle 3$: Subtract to isolate the binding energy.This is the step where units matter most — both terms must be in joules, at the same power of ten, before subtracting:\[E_{photon} = 1.3252 \times 10^{-15} \text{ J} = 13.252 \times 10^{-16} \text{ J} \] \[KE = 1.0248 \times 10^{-16} \text{ J} \]\[E_b = 13.252 \times 10^{-16} \text{ J} - 1.0248 \times 10^{-16} \text{ J} = 12.227 \times 10^{-16} \text{ J} \]\[E_b = 1.2227 \times 10^{-15} \text{ J} \]The input data ($\displaystyle 150$ pm, \(\displaystyle 1.5 \times 10^{7} \) m s\(\displaystyle ^{-1}\)) carries three significant figures at best, so round only now:\[E_b \approx 1.22 \times 10^{-15} \text{ J} \]Converting to electron-volts (dividing by \(\displaystyle 1.602 \times 10^{-19} \text{ J/eV} \)) gives a more familiar atomic-scale number:\[E_b = \dfrac{1.2227 \times 10^{-15} \text{ J}}{1.602 \times 10^{-19} \text{ J/eV}} \approx 7.63 \times 10^{3} \text{ eV} \]Answer: The electron is bound to the nucleus with energy \(\displaystyle E_b \approx 1.22 \times 10^{-15} \text{ J} \) (≈ \(\displaystyle 7.63 \times 10^{3} \) eV).
  5. Exercise 2.55

    Emission transitions in the Paschen series end at orbit n = 3\displaystyle 3 and start from orbit n and can be represeted as v = 3.29\displaystyle 3.29 × 1015\displaystyle 1015 (Hz) [1\displaystyle 1/32\displaystyle 321\displaystyle 1/n2] Calculate the value of n if the transition is observed at 1285\displaystyle 1285 nm. Find the region of the spectrum.
    NCERT’s answer
    infrared, $\displaystyle 5$
    Frequency and wavelength are linked by \(\displaystyle v = c/\lambda \), and you must convert nanometres to metres before you divide — leaving the exponent as \(\displaystyle 10^{-9}\) instead of folding it into the calculation is where this problem goes wrong.Step $\displaystyle 1$: Convert the given wavelength to metres.The wavelength is given in nanometres, but the speed of light \(\displaystyle c\) is in \(\displaystyle \text{m s}^{-1}\), so the units must match before you compute anything.\[\lambda = 1285 \text{ nm} = 1285 \times 10^{-9}\text{ m} = 1.285 \times 10^{-6}\text{ m} \]Step $\displaystyle 2$: Turn the wavelength into a frequency.Use \(\displaystyle v = \dfrac{c}{\lambda} \), where \(\displaystyle v\) is the frequency of the emitted radiation and \(\displaystyle c = 3 \times 10^{8}\text{ m s}^{-1}\) is the speed of light.\[v = \frac{3 \times 10^{8}\text{ m s}^{-1}}{1.285 \times 10^{-6}\text{ m}} = 2.3346 \times 10^{14}\text{ s}^{-1} \]Step $\displaystyle 3$: Set this frequency equal to the Paschen-series formula and solve for \(\displaystyle n\).You are told\[v = 3.29 \times 10^{15}\text{ Hz}\left[\frac{1}{3^{2}} - \frac{1}{n^{2}}\right] \]where \(\displaystyle 3\) is the fixed lower orbit (Paschen series always ends there) and \(\displaystyle n\) is the unknown higher orbit the electron falls from. Substitute the frequency from Step $\displaystyle 2$:\[2.3346 \times 10^{14} = 3.29 \times 10^{15}\left[\frac{1}{9} - \frac{1}{n^{2}}\right] \]Divide both sides by \(\displaystyle 3.29 \times 10^{15}\text{ Hz}\) to isolate the bracket:\[\frac{1}{9} - \frac{1}{n^{2}} = \frac{2.3346 \times 10^{14}}{3.29 \times 10^{15}} = 0.070961 \]Step $\displaystyle 4$: Solve for \(\displaystyle n^2\), then \(\displaystyle n\).This is the step where it's easy to lose track of which fraction is being subtracted from which — keep \(\displaystyle \frac{1}{n^2}\) on its own side.\[\frac{1}{n^{2}} = \frac{1}{9} - 0.070961 = 0.111111 - 0.070961 = 0.040150 \]\[n^{2} = \frac{1}{0.040150} = 24.91 \]\[n = \sqrt{24.91} = 4.99 \]Since \(\displaystyle n\) labels an electron orbit, it can only be a whole number — a fractional orbit has no physical meaning, so round \(\displaystyle 4.99\) to the nearest integer rather than truncating it.\[n = 5 \]Step $\displaystyle 5$: Identify the region of the spectrum.Every transition in the Paschen series (electron falling to \(\displaystyle n = 3\)) lies in the infrared region of the electromagnetic spectrum — this is true regardless of which upper orbit \(\displaystyle n\) the electron starts from, because all Paschen-series wavelengths fall between roughly $\displaystyle 820$ nm and $\displaystyle 1875$ nm, well outside the visible range ($\displaystyle 400$–$\displaystyle 700$ nm). The given wavelength of $\displaystyle 1285$ nm sits inside that infrared window, confirming the transition \(\displaystyle n = 5 \to n = 3\).Answer: \(\displaystyle n = 5\); the transition (\(\displaystyle 5 \to 3\)) lies in the infrared region of the spectrum.
  6. Exercise 2.56

    Calculate the wavelength for the emission transition if it starts from the orbit having radius 1.3225\displaystyle 1.3225 nm and ends at 211.6\displaystyle 211.6 pm. Name the series to which this transition belongs and the region of the spectrum.
    NCERT’s answer
    $\displaystyle 434$ nm
    The orbit radius tells you the principal quantum number \(\displaystyle n\) before it tells you anything else — read \(\displaystyle n\) off each radius first, then find which spectral series the jump belongs to.Step $\displaystyle 1$ — turn each radius into a quantum numberFor a one-electron (hydrogen-like) atom, the Bohr radius formula is\[r_n = \frac{n^2}{Z}\,a_0 , \qquad a_0 = 52.9\ \text{pm (the first Bohr radius)} \]where \(\displaystyle n\) is the principal quantum number of the orbit and \(\displaystyle Z\) is the atomic number. For hydrogen, \(\displaystyle Z=1\), so \(\displaystyle r_n = n^2 a_0\).Convert both given radii to picometres so they match \(\displaystyle a_0\):\[1.3225\ \text{nm} = 1322.5\ \text{pm}, \qquad 211.6\ \text{pm (already in pm)} \]Solve \(\displaystyle n^2 = r_n/a_0\) for the starting orbit:\[n_i^2 = \frac{1322.5\ \text{pm}}{52.9\ \text{pm}} = 25.00 \quad\Rightarrow\quad n_i = 5 \]and for the orbit the electron lands in:\[n_f^2 = \frac{211.6\ \text{pm}}{52.9\ \text{pm}} = 4.00 \quad\Rightarrow\quad n_f = 2 \]The transition is \(\displaystyle n=5 \rightarrow n=2\). Since the electron moves from the higher orbit (\(\displaystyle n=5\), larger radius, higher energy) down to the lower orbit (\(\displaystyle n=2\)), energy is released as a photon — consistent with the question calling this an emission transition.Step $\displaystyle 2$ — get the wavelength from the Rydberg formula\[\frac{1}{\lambda} = R_H\left(\frac{1}{n_f^2} - \frac{1}{n_i^2}\right) \]Here \(\displaystyle \lambda\) is the emitted wavelength, \(\displaystyle R_H = 1.097\times10^{7}\ \text{m}^{-1}\) is the Rydberg constant, \(\displaystyle n_f = 2\) is the final (lower) orbit and \(\displaystyle n_i = 5\) is the initial (higher) orbit. Put the smaller \(\displaystyle n\) — the orbit the electron ends up in — first inside the brackets; swapping the two gives a negative wavelength, which is the most common slip here.\[\frac{1}{\lambda} = 1.097\times10^{7}\ \text{m}^{-1}\left(\frac{1}{2^2} - \frac{1}{5^2}\right) = 1.097\times10^{7}\ \text{m}^{-1}\left(0.2500 - 0.0400\right) \]\[\frac{1}{\lambda} = 1.097\times10^{7}\ \text{m}^{-1} \times 0.2100 = 2.304\times10^{6}\ \text{m}^{-1} \]\[\lambda = \frac{1}{2.304\times10^{6}\ \text{m}^{-1}} = 4.341\times10^{-7}\ \text{m} \]Converting to nanometres (\(\displaystyle 1\ \text{m} = 10^{9}\ \text{nm}\)):\[\lambda = 4.341\times10^{-7}\ \text{m} \times 10^{9}\ \frac{\text{nm}}{\text{m}} = 434.1\ \text{nm} \]The input data (the Rydberg constant to $\displaystyle 4$ significant figures) justifies rounding to \(\displaystyle \lambda \approx 434\ \text{nm}\).Step $\displaystyle 3$ — name the series and the regionAny emission ending at \(\displaystyle n_f = 2\) belongs to the Balmer series. Wavelengths in the Balmer series fall in the range of roughly $\displaystyle 400$–$\displaystyle 700$ nm, which is the visible region of the electromagnetic spectrum — and $\displaystyle 434$ nm (a blue-violet line) sits right inside that range.Answer: \(\displaystyle \lambda \approx 434\ \text{nm}\); the transition \(\displaystyle n=5 \rightarrow n=2\) belongs to the Balmer series, in the visible region of the spectrum.
  7. Exercise 2.57

    Dual behaviour of matter proposed by de Broglie led to the discovery of electron microscope often used for the highly magnified images of biological molecules and other type of material. If the velocity of the electron in this microscope is 1.6\displaystyle 1.6 × 106\displaystyle 106 ms–1\displaystyle 1, calculate de Broglie wavelength associated with this electron.
    NCERT’s answer
    $\displaystyle 455$ pm
    The de Broglie relation turns a particle's momentum into a wavelength — it applies to the electron exactly the way it applies to a photon.The de Broglie wavelength is\[\lambda = \frac{h}{mv} \]where \(\displaystyle h\) is Planck's constant, \(\displaystyle m\) is the mass of the particle, and \(\displaystyle v\) is its speed. The product \(\displaystyle mv\) is the particle's momentum — everything about "matter waves" is packed into that one denominator.List the knowns, and don't confuse the electron's mass with the mass of a mole of electrons.\[h = 6.626 \times 10^{-34}\ \text{J s}, \qquad m_e = 9.11 \times 10^{-31}\ \text{kg}, \qquad v = 1.6 \times 10^{6}\ \text{m s}^{-1} \]The mass here is the rest mass of a single electron, not molar mass — mixing that up is the single most common slip in this calculation.Substitute directly into \(\displaystyle \lambda = h/(mv)\), keeping every unit attached.First find the momentum, \(\displaystyle mv\):\[mv = (9.11 \times 10^{-31}\ \text{kg})(1.6 \times 10^{6}\ \text{m s}^{-1}) = 1.4576 \times 10^{-24}\ \text{kg m s}^{-1} \]Now divide \(\displaystyle h\) by this momentum:\[\lambda = \frac{6.626 \times 10^{-34}\ \text{J s}}{1.4576 \times 10^{-24}\ \text{kg m s}^{-1}} \]Since \(\displaystyle 1\ \text{J} = 1\ \text{kg m}^2\text{s}^{-2}\), the units work out as\[\frac{\text{kg m}^2\text{s}^{-2}\cdot \text{s}}{\text{kg m s}^{-1}} = \text{m} \]confirming the result comes out in metres, as a wavelength must.\[\lambda = \frac{6.626 \times 10^{-34}}{1.4576 \times 10^{-24}}\ \text{m} = 4.546 \times 10^{-10}\ \text{m} \]Round once, at the end, to the precision the data supports.The speed was given as \(\displaystyle 1.6 \times 10^6\ \text{m s}^{-1}\) (three significant figures counting the trailing digits as meaningful, as is standard for this problem), so the answer is reported to three significant figures:\[\lambda \approx 4.55 \times 10^{-10}\ \text{m} \]This is the same as \(\displaystyle 455\ \text{pm}\) or \(\displaystyle 0.455\ \text{nm}\) — a length comparable to atomic dimensions, which is exactly why electron microscopes (using electrons of this wavelength) can resolve detail far finer than a light microscope, whose wavelength is thousands of times longer.Answer: \(\displaystyle \lambda \approx 4.55 \times 10^{-10}\ \text{m}\) (i.e., \(\displaystyle 455\ \text{pm}\))
  8. Exercise 2.58

    Similar to electron diffraction, neutron diffraction microscope is also used for the determination of the structure of molecules. If the wavelength used here is 800\displaystyle 800 pm, calculate the characteristic velocity associated with the neutron.
    NCERT’s answer
    494.$\displaystyle 5$ ms–$\displaystyle 1$
    Every moving particle has a wavelength attached to it — de Broglie's relation connects that wavelength to the particle's momentum, and momentum is just mass times velocity.The de Broglie relation is \[\lambda = \frac{h}{mv} \] where \(\displaystyle \lambda\) is the wavelength of the particle, \(\displaystyle h\) is Planck's constant, \(\displaystyle m\) is the mass of the particle, and \(\displaystyle v\) is its velocity. Rearranging for the velocity gives \[v = \frac{h}{m\lambda} \]The values needed:
    Planck's constant, \(\displaystyle h = 6.626 \times 10^{-34}\ \text{J s}\)
    Mass of a neutron, \(\displaystyle m = 1.675 \times 10^{-27}\ \text{kg}\)
    Wavelength, \(\displaystyle \lambda = 800\ \text{pm} = 800 \times 10^{-12}\ \text{m} = 8.00 \times 10^{-10}\ \text{m}\)
    The step people skip here is the unit conversion on \(\displaystyle \lambda\) — picometres must become metres before the substitution, otherwise every power of ten downstream is wrong.Substituting into \(\displaystyle v = \dfrac{h}{m\lambda}\):First find the denominator, \(\displaystyle m\lambda\): \[m\lambda = (1.675 \times 10^{-27}\ \text{kg})(8.00 \times 10^{-10}\ \text{m}) = 1.340 \times 10^{-36}\ \text{kg m} \]Now divide \(\displaystyle h\) by this: \[v = \frac{6.626 \times 10^{-34}\ \text{J s}}{1.340 \times 10^{-36}\ \text{kg m}} \]Since \(\displaystyle 1\ \text{J} = 1\ \text{kg m}^2\text{s}^{-2}\), the units work out to \[\frac{\text{kg m}^2\text{s}^{-2}\cdot \text{s}}{\text{kg m}} = \text{m s}^{-1} \] which is exactly what a velocity should come out as — a useful check that no unit was dropped along the way.Carrying out the division: \[v = \frac{6.626}{1.340} \times 10^{-34-(-36)}\ \text{m s}^{-1} = 4.945 \times 10^{2}\ \text{m s}^{-1} \]The data (wavelength given to $\displaystyle 3$ significant figures) justifies rounding to $\displaystyle 3$ significant figures.\[v \approx 494\ \text{m s}^{-1} \]**Answer: The neutron's characteristic velocity is \(\displaystyle v \approx 494\ \text{m s}^{-1}\) (\(\displaystyle 4.94 \times 10^{2}\ \text{m s}^{-1}\)), found from the de Broglie relation \(\displaystyle v = h/(m\lambda)\) using the neutron's rest mass \(\displaystyle 1.675 \times 10^{-27}\ \text{kg}\).
  9. Exercise 2.59

    If the velocity of the electron in Bohr’s first orbit is 2.19\displaystyle 2.19 × 106\displaystyle 106 ms–1\displaystyle 1, calculate the de Broglie wavelength associated with it.
    NCERT’s answer
    $\displaystyle 332$ pm
    The de Broglie relation turns a particle's momentum into a wavelength: \(\displaystyle \lambda = \dfrac{h}{mv} \).Here \(\displaystyle \lambda \) is the de Broglie wavelength, \(\displaystyle h \) is Planck's constant, \(\displaystyle m \) is the mass of the particle, and \(\displaystyle v \) is its speed. For an electron you need its rest mass, \(\displaystyle m_e = 9.10939 \times 10^{-31}\ \text{kg} \), and Planck's constant, \(\displaystyle h = 6.626 \times 10^{-34}\ \text{J s} \).A short aside on units before substituting: \(\displaystyle 1\ \text{J} = 1\ \text{kg m}^2\text{s}^{-2} \), so \(\displaystyle h \) carries units of \(\displaystyle \text{kg m}^2\text{s}^{-1} \). Dividing by \(\displaystyle mv \) (units \(\displaystyle \text{kg} \times \text{m s}^{-1} = \text{kg m s}^{-1} \)) leaves plain metres — that unit bookkeeping is what confirms the substitution is set up correctly, not just numerically.Given: \(\displaystyle v = 2.19 \times 10^{6}\ \text{m s}^{-1} \).First, the denominator, \(\displaystyle mv \): \[m_e v = (9.10939 \times 10^{-31}\ \text{kg})(2.19 \times 10^{6}\ \text{m s}^{-1}) \]Multiply the coefficients and add the exponents separately: \[9.10939 \times 2.19 = 19.9496 \] \[m_e v = 19.9496 \times 10^{-31+6}\ \text{kg m s}^{-1} = 19.9496 \times 10^{-25}\ \text{kg m s}^{-1} = 1.99496 \times 10^{-24}\ \text{kg m s}^{-1} \]Now divide \(\displaystyle h \) by this momentum: \[\lambda = \frac{6.626 \times 10^{-34}\ \text{kg m}^2\text{s}^{-1}}{1.99496 \times 10^{-24}\ \text{kg m s}^{-1}} \]Divide the coefficients and subtract the exponents: \[\frac{6.626}{1.99496} = 3.3214 \] \[\lambda = 3.3214 \times 10^{-34-(-24)}\ \text{m} = 3.3214 \times 10^{-10}\ \text{m} \]The given speed has three significant figures, so the answer is rounded to three: \(\displaystyle \lambda = 3.32 \times 10^{-10}\ \text{m} \), which is the same length as \(\displaystyle 332\ \text{pm} \).That the electron's own orbit radius (about $\displaystyle 53$ pm for the first Bohr orbit) is smaller than this wavelength is exactly the point of de Broglie's idea — a wave of this size fitting around the orbit is what forces the orbit's radius, and hence its energy, to be quantized rather than continuous. That connection between wavelength and quantized orbits is why this calculation matters, not merely the number itself.Answer: \(\displaystyle \lambda = 3.32 \times 10^{-10}\ \text{m} = 332\ \text{pm} \)
  10. Exercise 2.60

    The velocity associated with a proton moving in a potential difference of 1000\displaystyle 1000 V is 4.37\displaystyle 4.37 × 105\displaystyle 105 ms–1. If the hockey ball of mass 0.1\displaystyle 0.1 kg is moving with this velocity, calcualte the wavelength associated with this velocity.
    NCERT’s answer
    1.$\displaystyle 516$ × $\displaystyle 10$–$\displaystyle 38$ m
    The de Broglie relation \(\displaystyle \lambda = \dfrac{h}{mv} \) applies to every moving object — a proton or a hockey ball — but the mass in the denominator is what decides whether the wavelength is ever noticeable.The proton's speed is only there to tell you what velocity to plug in for the hockey ball — you are not being asked to re-derive it from the potential difference. Once a velocity is handed to you, the wavelength calculation is the same formula every time:\[\lambda = \frac{h}{mv} \]where \(\displaystyle \lambda \) is the de Broglie wavelength (in m), \(\displaystyle h \) is Planck's constant, \(\displaystyle 6.626 \times 10^{-34}\ \text{J s} \), \(\displaystyle m \) is the mass of the moving object (in kg), and \(\displaystyle v \) is its speed (in m s\(\displaystyle ^{-1}\)).Values for the hockey ball: \[m = 0.1\ \text{kg}, \qquad v = 4.37 \times 10^{5}\ \text{m s}^{-1} \]Both are already in SI units (kg and m s\(\displaystyle ^{-1}\)), so no conversion is needed before substituting — this is the step that trips people up when a mass is given in grams instead of kilograms, but here it isn't.First find the momentum \(\displaystyle mv \): \[mv = 0.1\ \text{kg} \times 4.37 \times 10^{5}\ \text{m s}^{-1} = 4.37 \times 10^{4}\ \text{kg m s}^{-1} \]Now substitute into the de Broglie formula: \[\lambda = \frac{6.626 \times 10^{-34}\ \text{J s}}{4.37 \times 10^{4}\ \text{kg m s}^{-1}} \]Divide the coefficients and subtract the exponents: \[\lambda = \frac{6.626}{4.37} \times 10^{-34-4}\ \text{m} = 1.516 \times 10^{-38}\ \text{m} \](A joule is a kg m\(\displaystyle ^2\) s\(\displaystyle ^{-2}\), so J s / (kg m s\(\displaystyle ^{-1}\)) reduces cleanly to metres — the units check out.)The input data (\(\displaystyle 4.37 \times 10^{5}\)) carries three significant figures, so the answer is reported to the same precision: \(\displaystyle \lambda \approx 1.516 \times 10^{-38}\ \text{m} \).This number is roughly \(\displaystyle 10^{23}\) times smaller than the size of a proton itself — far below anything any instrument could ever detect. That is the real point of the calculation: because wavelength is inversely proportional to mass, a proton's wave nature is measurable while a hockey ball's is not, even at the same speed.Answer: \(\displaystyle \lambda \approx 1.516 \times 10^{-38}\ \text{m} \)