CBSE 2023 · Region 5 · Set 1 · Q13 · 1 mark
The following experimental rate data were obtained for a reaction carried out at $\displaystyle 25$ °C : $\displaystyle \mathrm{A}_{(\mathrm{g})}+\mathrm{B}_{(\mathrm{g})} \rightarrow \mathrm{C}_{(\mathrm{g})}+\mathrm{D}_{(\mathrm{g})}$ Initial $\displaystyle \left[\mathrm{A}_{(\mathrm{g})}\right] / \mathrm{mol} \mathrm{dm}^{-3}$ Initial $\displaystyle \left[\mathrm{B}_{(\mathrm{g})}\right] / \mathrm{mol} \mathrm{dm}^{-3}$ Initial rate/mol $\displaystyle \mathrm{dm}^{-3} \mathrm{~s}^{-1}$ $\displaystyle 3.0 \times 10^{-2}$ $\displaystyle 2.0 \times 10^{-2}$ $\displaystyle 1.89 \times 10^{-4}$ $\displaystyle 3.0 \times 10^{-2}$ $\displaystyle 4.0 \times 10^{-2}$ $\displaystyle 1.89 \times 10^{-4}$ $\displaystyle 6.0 \times 10^{-2}$ $\displaystyle 4.0 \times 10^{-2}$ $\displaystyle 7.56 \times 10^{-4}$
What are the orders with respect to $\displaystyle \mathrm{A}_{(\mathrm{g})}$ and $\displaystyle \mathrm{B}_{(\mathrm{g})}$ ?(a)Order with respect to $\displaystyle \mathrm{A}_{(\mathrm{g})}$ Order with respect to $\displaystyle \mathrm{B}_{(\mathrm{g})}$ Zero Second First Zero Second Zero Second First
The following experimental rate data were obtained for a reaction carried out at $\displaystyle 25$ °C : $\displaystyle \mathrm{A}_{(\mathrm{g})}+\mathrm{B}_{(\mathrm{g})} \rightarrow \mathrm{C}_{(\mathrm{g})}+\mathrm{D}_{(\mathrm{g})}$
What are the orders with respect to $\displaystyle \mathrm{A}_{(\mathrm{g})}$ and $\displaystyle \mathrm{B}_{(\mathrm{g})}$ ?
| Initial $\displaystyle \left[\mathrm{A}_{(\mathrm{g})}\right] / \mathrm{mol} \mathrm{dm}^{-3}$ | Initial $\displaystyle \left[\mathrm{B}_{(\mathrm{g})}\right] / \mathrm{mol} \mathrm{dm}^{-3}$ | Initial rate/mol $\displaystyle \mathrm{dm}^{-3} \mathrm{~s}^{-1}$ |
| $\displaystyle 3.0 \times 10^{-2}$ | $\displaystyle 2.0 \times 10^{-2}$ | $\displaystyle 1.89 \times 10^{-4}$ |
| $\displaystyle 3.0 \times 10^{-2}$ | $\displaystyle 4.0 \times 10^{-2}$ | $\displaystyle 1.89 \times 10^{-4}$ |
| $\displaystyle 6.0 \times 10^{-2}$ | $\displaystyle 4.0 \times 10^{-2}$ | $\displaystyle 7.56 \times 10^{-4}$ |
(a)
| Order with respect to $\displaystyle \mathrm{A}_{(\mathrm{g})}$ | Order with respect to $\displaystyle \mathrm{B}_{(\mathrm{g})}$ |
| Zero | Second |
| First | Zero |
| Second | Zero |
| Second | First |
Official answer
From CBSE’s own marking scheme for this paper.
(C)
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CBSE Class 12 Chemistry past-paper question from the 2023board exam, with the answer as CBSE’s own marking scheme gives it. Where our answers come from.