Exercise 23
You are provided with a mixture of naphthalene and ammonium chloride
by your teacher. Suggest an activity to separate them with well labelled
diagram.
Matches the book, not yet reviewed
This working reaches the answer NCERT prints. It has not yet been read through by hand.
NCERT’s answer
Hint— Naphthalene is insoluble in water but soluble in ether an organic solvent. It is volatile at room temperature. Ammonium chloride is soluble in water and volatile at higher temperature. It decomposes on heating to dryness.
Add water to the mixture and stir; \(\displaystyle \text{NH}_4\text{Cl}\) is water-soluble, naphthalene is not.
Filter the mixture: naphthalene stays on the filter paper as residue, the \(\displaystyle \text{NH}_4\text{Cl}\) solution passes through as filtrate.
Warm the filtrate gently in a china dish and stop short of dryness — strong heating carries \(\displaystyle \text{NH}_4\text{Cl}\) away as sublimate too.
Cool the concentrated solution to crystallise out solid \(\displaystyle \text{NH}_4\text{Cl}\).
Answer: Naphthalene is recovered as the filter residue, ammonium chloride as the crystallised filtrate.