CBSE 2022 · Region 3 · Set 3 · Q10 · 3 marks
(a)Using valence bond theory, predict the hybridization and magnetic character of the complex : $\displaystyle \left[\mathrm{Ni}(\mathrm{CO})_{4}\right]$ (Atomic number : $\displaystyle \mathrm{Ni}=28$ )(b)Write IUPAC name of $\displaystyle \left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}\left(\mathrm{NO}_{2}\right)\right]$.(c)Why $\displaystyle \left[\mathrm{Co}(\mathrm{en})_{3}\right]^{3+}$ is a more stable complex than $\displaystyle \left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+} ? \quad$
(a)
Using valence bond theory, predict the hybridization and magnetic character of the complex :
$\displaystyle \left[\mathrm{Ni}(\mathrm{CO})_{4}\right]$ (Atomic number : $\displaystyle \mathrm{Ni}=28$ )
(b)
Write IUPAC name of $\displaystyle \left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}\left(\mathrm{NO}_{2}\right)\right]$.
(c)
Why $\displaystyle \left[\mathrm{Co}(\mathrm{en})_{3}\right]^{3+}$ is a more stable complex than $\displaystyle \left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+} ? \quad$
Marking-scheme solution
(a) \(\displaystyle s p^{3}\), diamagnetic
(b) diamminechloridonitrito- \(\displaystyle N\)-platinum (II)
(c) Because of chelate effect / due to cyclic structure.
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CBSE Class 12 Chemistry past-paper question from the 2022board exam, with the answer as CBSE’s own marking scheme gives it. Where our answers come from.