CBSE 2025 · Region 2 · Set 3 · Q25 · 3 marks
(a)Using valence bond theory, explain the hybridization and magnetic behaviour of the following : $\displaystyle \mathbf{2}+\mathbf{1}=\mathbf{3}$(i)$\displaystyle \left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{C} l_{3}$(ii)$\displaystyle \mathrm{K}_{2}\left[\mathrm{NiCl}_{4}\right]$ [At. no. : $\displaystyle \mathrm{Co}=27, \mathrm{Ni}=28$ ](b)Write the electronic configuration of $\displaystyle \mathrm{d}^{5}$ ion when $\displaystyle \Delta_{\mathrm{o}}>\mathrm{P}$.
(a)
Using valence bond theory, explain the hybridization and magnetic behaviour of the following : $\displaystyle \mathbf{2}+\mathbf{1}=\mathbf{3}$
(i)
$\displaystyle \left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{C} l_{3}$
(ii)
$\displaystyle \mathrm{K}_{2}\left[\mathrm{NiCl}_{4}\right]$ [At. no. : $\displaystyle \mathrm{Co}=27, \mathrm{Ni}=28$ ]
(b)
Write the electronic configuration of $\displaystyle \mathrm{d}^{5}$ ion when $\displaystyle \Delta_{\mathrm{o}}>\mathrm{P}$.
Marking-scheme solution
(i)
Hybridization: d2sp3
Magnetic character: Diamagnetic.
(ii)
Hybridization: sp3
Magnetic character: Paramagnetic.
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CBSE Class 12 Chemistry past-paper question from the 2025board exam, with the answer as CBSE’s own marking scheme gives it. Where our answers come from.