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Chemistry · 2022 · 2 marks
CBSE 2022 · Region 3 · Set 3 · Q3
The conductivity of 0.001M acetic acid is 7.8 × 10^-5 S cm^-1. Calculate its degree of dissociation if Λ^° m for acetic acid is 390 S cm^2 mol^-1.
The conductivity of 0.001M acetic acid is $\displaystyle 7.8 \times 10^{-5} \mathrm{~S} \mathrm{~cm}^{-1}$. Calculate its degree of dissociation if $\displaystyle \mathbf{\Lambda}^{\circ} \mathrm{m}$ for acetic acid is $\displaystyle 390 \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}$.
Marking-scheme solution
\[\begin{aligned}
\mathbf{\Lambda}_{\mathrm{m}} & =\frac{\mathrm{k}}{C} \times 1000 \Omega^{-1} \mathrm{~cm}^{2} \mathrm{~mol}^{-1} \\
& =\frac{7 \cdot 8 \times 10^{-5}}{0.001} \times 1000 \Omega^{-1} \mathrm{~cm}^{2} \mathrm{~mol}^{-1} \\
& =78 \Omega^{-1} \mathrm{~cm}^{2} \mathrm{~mol}^{-1} \text { or } 78 \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1} \\
\alpha & =\frac{\mathbf{\Lambda}_{\mathrm{m}}}{\mathbf{\Lambda}_{\mathrm{m}}^{\circ}} \\
& =\frac{78}{390}=0.2
\end{aligned}
\]
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CBSE Class 12 Chemistry past-paper question from the 2022 board exam, with the answer as CBSE’s own marking scheme gives it. Where our answers come from.