CBSE 2022 · Region 5 · Set 1 · Q3 · 2 marks
Explain the following reactions :(a)Wolff Kishner reduction(b)Cannizzaro reaction
Explain the following reactions :
(a)
Wolff Kishner reduction
(b)
Cannizzaro reaction
Marking-scheme solution
(a)
$\displaystyle {\mathrm{H_3C}\atop\mathrm{H_3C}}\mkern-6mu{\diagdown\atop\diagup}\mkern-4mu\mathrm{C}{=}\mathrm{O} + \mathrm{NH_2NH_2} \longrightarrow {\mathrm{H_3C}\atop\mathrm{H_3C}}\mkern-6mu{\diagdown\atop\diagup}\mkern-4mu\mathrm{C}{=}\mathrm{NNH_2} \xrightarrow[\Delta]{\text{KOH, ethylene glycol}} \mathrm{CH_3{-}CH_2{-}CH_3} + \mathrm{N_2}$
(b)
$\displaystyle 2\,\mathrm{HCHO} \xrightarrow{\ \text{conc. KOH}\ } \mathrm{CH_3OH} + \mathrm{HCOO^-K^+}$
Aldehydes, Ketones and Carboxylic AcidsChemical Reactions of Aldehydes, Ketones and Carboxylic AcidsUnderstandvery_short_answermedium
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