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CBSE 2025 · Region 4 · Set 2 · Q23 · 3 marks

Arrange the following compounds as asked :
(a)
in increasing order of $\displaystyle \mathrm{pK}_{\mathrm{b}}$ values $\displaystyle \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}, \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NHCH}_{3}, \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}$
(b)
in decreasing order of boiling point $\displaystyle \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}, \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
(c)
in decreasing order of solubility in water $\displaystyle \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}, \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}$

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