CBSE 2025 · Region 4 · Set 2 · Q23 · 3 marks
Arrange the following compounds as asked :(a)in increasing order of $\displaystyle \mathrm{pK}_{\mathrm{b}}$ values $\displaystyle \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}, \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NHCH}_{3}, \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}$(b)in decreasing order of boiling point $\displaystyle \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}, \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$(c)in decreasing order of solubility in water $\displaystyle \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}, \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}$
Arrange the following compounds as asked :
(a)
in increasing order of $\displaystyle \mathrm{pK}_{\mathrm{b}}$ values $\displaystyle \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}, \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NHCH}_{3}, \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}$
(b)
in decreasing order of boiling point $\displaystyle \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}, \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
(c)
in decreasing order of solubility in water $\displaystyle \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2},\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}, \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}$
Marking-scheme solution
(a)
C2H5)2NH< C2H5NH2 <C6H5NHCH3 <C6H5NH2
(b)
C2H5OH> C2H5NH2>(CH3)2NH
(c)
C2H5NH2>(C2H5)2NH2> C6H5NH2
AminesPhysical Properties of AminesAnalyseshort_answermedium
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CBSE Class 12 Chemistry past-paper question from the 2025board exam, with the answer as CBSE’s own marking scheme gives it. Where our answers come from.