CBSE 2025 · Region 6 · Set 1 · Q27 · 3 marks
A compound (A) with molecular formula $\displaystyle \mathrm{C}_{4} \mathrm{H}_{5} \mathrm{~N}$ on reduction with DIBAL-H followed by hydrolysis, gives a compound (B). Compound (B) gives positive Tollens' test but does not give iodoform test. Compound (B) can also be obtained when ethanal is treated with dilute NaOH followed by heating. Identify (A) and (B). Write the reactions of (A) with DIBAL-H followed by hydrolysis.
Marking-scheme solution
A= CH3CH=CHCN / But-$\displaystyle 2$-ene nitrile
B= CH3CH=CHCHO / But-$\displaystyle 2$-enal
CH3CH=CHCN
CH3CH=CHCHO
Aldehydes, Ketones and Carboxylic AcidsPreparation of Aldehydes and KetonesAnalyseshort_answerhard
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