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Chemistry · 2022

JEE Main · 28 June 2022, Shift 1 · Q69

Given below are two statements: Statement I: [ Ni ( CN )_4]^2- is square planar and diamagnetic complex, with dsp^2 hybridization for Ni but [ Ni (…

Given below are two statements : Statement I : $\displaystyle \left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ is square planar and diamagnetic complex, with $\displaystyle \mathrm{dsp}^2$ hybridization for Ni but $\displaystyle \left[\mathrm{Ni}(\mathrm{CO})_4\right]$ is tetrahedral, paramagnetic and with $\displaystyle \mathrm{sp}^3$ - hybridication for Ni . Statement II : $\displaystyle \left[\mathrm{NiCl}_4\right]^{2-}$ and $\displaystyle \left[\mathrm{Ni}(\mathrm{CO})_4\right]$ both have same d-electron configuration, have same geometry and are paramagnetic.In light the above statements, choose the correct answer form the options given below:
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JEE Main 2022 Chemistry question, with the answer from NTA’s final answer key. Where our answers come from.