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Chemistry · 2020

JEE Main · 7 January 2020, Shift 2 · Q38

Among the statements (a)-(d), the incorrect ones are: (a) Octahedral Co(III) complexes with strong field ligands have very high magnetic moments (b)…

Among the statements (a)-(d), the incorrect ones are :
(a)
Octahedral Co(III) complexes with strong field ligands have very high magnetic moments
(b)
When $\displaystyle \Delta_0<\mathrm{P}$, the d-electron configuration of Co(III) in an octahedral complex is $\displaystyle \mathrm{t}_{\mathrm{eg}}^4 \mathrm{e}_{\mathrm{g}}^2$
(c)
Wavelength of light absorbed by $\displaystyle \left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}$ is lower than that of $\displaystyle \left[\mathrm{CoF}_6\right]^{3-}$
(d)
If the $\displaystyle \Delta_0$ for an octahedral complex of $\displaystyle \operatorname{Co}$ (III) is $\displaystyle 18,000 \mathrm{~cm}^{-1}$, the $\displaystyle \Delta_{\mathrm{t}}$ for its tetrahedral complex with the same ligand will be $\displaystyle 16,000 \mathrm{~cm}^{-1}$
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JEE Main 2020 Chemistry question, with the answer from NTA’s final answer key. Where our answers come from.